Am having the same issue.
Tried deleting both 13.4.1 and 14b3, all related caches, clean project, delete all in Library/Developer/Xcode/*, reinstalling, rebooting in-between and I'm still unable to open any .xib/.storyboard.
xcode-select -p is showing the correct path as well... Incredibly frustrating this.
Topic:
Developer Tools & Services
SubTopic:
Xcode
Tags: