I was able to track down the files in question, in case anyone else in the future needs to know.
For StoreKit testing on Mac catalyst, check the directory:
~/Library/Caches/com.apple.appstoreagent/Octane
The sqlite file store.db contains a table octane_transaction with the transactions in question, and I was able to delete my 23,000 test transactions from it.
Topic:
App & System Services
SubTopic:
StoreKit
Tags: